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Partial photoionization cross sections of and Rydberg radicals


Metadata FieldValueLanguage
dc.contributorJ.V. Ortiz, jvo0001@auburn.eduen_US
dc.creatorVelasco, A.M.
dc.creatorLavin, C.
dc.creatorMartin, I.
dc.creatorMelin, J.
dc.creatorOrtiz, J.V.
dc.date.accessioned2021-01-26T18:23:00Z
dc.date.available2021-01-26T18:23:00Z
dc.date.created2009
dc.identifier10.1063/1.3168397en_US
dc.identifier.urihttps://aip.scitation.org/doi/pdf/10.1063/1.3168397en_US
dc.identifier.urihttps://aurora.auburn.edu/handle/11200/49957
dc.identifier.urihttp://dx.doi.org/10.35099/aurora-31
dc.description.abstractammonium and oxonium Rydberg radicals from the outermost, occupied orbitals of their respective ground states are reported. These properties are known to be relevant in photoelectron dynamics studies. For the present calculations, the molecular-adapted quantum defect orbital method has been employed. A Cooper minimum has been found in the 3sa1-kpt2 Rydberg channel of NH4 beyond the ionization threshold, which provides the main contribution to the photoionization of this radical. However, no net minimum is found in the partial cross section of H3O despite the presence of minima in the 3sa1-kpe and 3sa1-kpa1 Rydberg channels. The complete oscillator strength distributions spanning the discrete and continuous regions of both radicals exhibit the expected continuity across the ionization threshold.en_US
dc.formatPDFen_US
dc.publisherAIP Publishingen_US
dc.relation.ispartofJournal of Chemical Physicsen_US
dc.relation.ispartofseries0021-9606en_US
dc.rights© 2009. This is the version of record published by AIP Publishing and is made available under the CC-BY-NC-ND 4.0 license. Item should be cited as: J. Chem. Phys. 131, 024104 (2009); https://doi.org/10.1063/1.3168397 Submitted: 03 April 2009 . Accepted: 12 June 2009 . Published Online: 08 July 2009 :Partial photoionization cross sections of and Rydberg radicals :A. M. Velasco, C. Lavín, I. Martín, J. Melin, and J. V. Ortizen_US
dc.titlePartial photoionization cross sections of and Rydberg radicalsen_US
dc.typeTexten_US
dc.type.genreJournal Article, Academic Journalen_US
dc.citation.volume131en_US
dc.citation.spage024104-1en_US
dc.citation.epage024104-6en_US
dc.description.statusPublisheden_US
dc.description.peerreviewYesen_US

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